"Cosmos" by Carl Sagan on, well, the cosmos, and "The Code Book" by Simon Singh on the history of the science of secrecy are excellent too, but these have quite a wide breadth.
E=mc squared - David Bodanis
Quantum Physics and Theology - John Polkinghorne
The Black Hole War: My Battle with Stephen Hawking to Make the World Safe for Quantum Mechanics, by Leonard Susskind ---- More than anything, the title sucks you in... kinda like a blackhole
Physics of the Impossible: A Scientific Exploration into the World of Phasers, Force Fields, Teleportation, and Time Travel by Michio Kaku --- this just looks cool, as does the Parallel Worlds that Dave C mentioned earlier.
Death from the Skies -Philip Plait
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